Process for preparing ammonium zeolites of low alkali metal cont

Chemistry of inorganic compounds – Zeolite

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423DIG21, 502 86, C01B 3920

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054359872

ABSTRACT:
Ammonium zeolites of extremely low alkali metal content are prepared by a process of potassium ion exchange followed by ammonium ion exchange. Zeolite X or zeolite Y that contain a significant amount of sodium are contacted with a potassium salt solution under conditions that provide a substantial exchange of potassium for sodium. The potassium enriched zeolite is then contacted with an ammonium salt solution so that the ammonium ion replaces the sodium and potassium ions. The resulting ammonium zeolite X or Y contains considerably less than 1% alkali metal calculated as Na.sub.2 O.

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Sherry "The Ion Exchange Properties of Zeolites. I Univalent Ion Exchange in Synthetic Faujasite" J. Phys. Chem. vol. 70 No. 4 Apr. '66.

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