Process of preparing substituted acrylates

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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560118, 560146, 560193, 560197, 560201, C07D30316, C07C 6952

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active

040565432

ABSTRACT:
Methylenemalonates are prepared by reacting a substituted norbornene with an electrophilic material in the presence of a lithium amide complex and pyrolyzing. The resulting acrylates are useful as fast setting, polymerizable adhesives.

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Feely et al., Organic Synthesis, 38, pp. 22-25, (1955).
Brocksom et al., J. Org. Chem. 39, No. 14, p. 2114-2116, (1974).

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