Chemistry: electrical current producing apparatus – product – and – Current producing cell – elements – subcombinations and... – Include electrolyte chemically specified and method
Patent
1993-10-08
1995-08-01
Kalafut, Stephen
Chemistry: electrical current producing apparatus, product, and
Current producing cell, elements, subcombinations and...
Include electrolyte chemically specified and method
429223, 429224, H01M 1040
Patent
active
054379458
ABSTRACT:
A secondary battery which employs a non-aqueous solvent for the electrolyte and which includes a positive electrode formed of a compound oxide of lithium and a negative electrode of a carbonaceous material is disclosed. The non-aqueous electrolyte, comprised of an electrolyte dissolved in the non-aqueous solvent, is employed in such secondary battery. According to the present invention, a mixed solvent composed of propylene carbonate and methyl ethyl carbonate is employed. The volume ratio of propylene carbonate to methyl ethyl carbonate is 6:4 to 3:7 and preferably 4.5:5.5 to 3:7. As the electrolyte, LiPF.sub.6 is dissolved at a concentration of 0.6 to 1.8 mol/lit. The battery is not increased in its internal pressure even when employed under a high temperature environment, while its electrolyte is not solidified when the battery is employed under a low temperature environment, such that a high energy density, a long service life and high operating reliability may be achieved over a broad range of the working temperature.
REFERENCES:
patent: 3544385 (1970-12-01), Newman
patent: 5192629 (1993-03-01), Guyomard et al.
patent: 5264201 (1993-11-01), Dahn et al.
patent: 5292601 (1994-03-01), Sugeno et al.
Fujita Shigeru
Omaru Atsuo
Kalafut Stephen
Sony Corporation
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