Coloration of acetylenic monomers by gases

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526235, 526236, 526237, 526238, 526285, 2524081, 116207, 116216, C08F 200, C08F 400, C09K 300

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045501505

ABSTRACT:
Process of detecting the presence of certain gases, including certain pollutants, in small concentrations; or to cause partial polymerization of certain polyacetylene compositions for use in time/temperature history indicators or radiation dosage indicators. The process involves contacting a reactive gas, such as a nitrogen oxide, a halide or ozone, with a crystalline substituted acetylenic monomer containing at least two conjugated triple bonds and substituents having at least one atom of oxygen or nitrogen. In particular the acetylenic compound is 2,4-hexadiyne-1,6-bis(phenylurethane) crystallized from tetrahydrofuran or acetone.

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patent: 4215208 (1980-07-01), Yee et al.
patent: 4373032 (1983-02-01), Preziosi et al.
patent: 4487709 (1984-12-01), Kobayashi et al.

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