Compositions curable by in situ generation of cations

Adhesive bonding and miscellaneous chemical manufacture – Methods – Surface bonding and/or assembly therefor

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1563073, 156327, 156330, 526144, 526195, 526204, 528 88, 528 89, 528 91, 528 93, 528 94, 528361, 528408, 528410, C08F 406, C08G 5968

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047174404

ABSTRACT:
A two-part composition curable by contact of respective parts with one another, comprising: a first part comprising a cationically polymerizable material and a first latent curing component; and a second part comprising a cationically polymerizable material and a second latent curing component which is reactive with the first component to form cations which are curingly effective for the resin. A preferred class of cation species comprises carbenium ions derived from reaction of organic halide compounds, as the first component, with silver salts of non-nucleophilic anions, e.g., SbCl.sub.6.sup.-, SbCl.sub.3.sup.-, SbF.sub.6.sup.-, AsF.sub.6.sup.-, SnCl.sub.5.sup.-, PF.sub.6.sup.-, BF.sub.4.sup.-, CF.sub.3 SO.sub.3.sup.- and ClO.sub.4.sup.-, as the second component, The respective parts of the two-part composition may be applied to matable surfaces which then are contacted to effect rapid bonding cure of the composition.

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H. K. Hall, Jr. and T. Gotoh, "Zwitterionic Tetramethylene Intermediates: A New Interpretation for `Charge Transfer` Initiation", Polymer Preprints, ACS Div. of Polymer Chemistry, vol. 26, No. 1, pp. 34-35, (1985).

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