Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1974-12-16
1977-07-26
Love, Ethel G.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
71 98, 106 2, 162168N, 260 775CR, 260453A, 260453RL, 260455A, 260534R, 260543P, 260553A, 260557R, 260874, 260938, C07C12503
Patent
active
040383113
ABSTRACT:
The production of N-(1-alkenyl)-carbamyl chlorides by reaction of a Schiff base with phosgene, and the new N-(1-alkenyl)-carbamyl chlorides themselves. The new compounds which can be prepared by the process of the invention are valuable starting materials for the production of coating intermediates, plastics, paints and plant protection agents.
One preferred group of compounds available from said process are the N-vinyl compounds of the formula ##STR1## in which R.sup.1 is cyclohexyl, cyclooctyl, norbornyl, tetrahydrodicyclopentadienyl, n-hexyl, n-octyl, 2-ethylhexyl or phenyl. Another preferred group of compounds are the N-vinyl-N-t-alkylcarbamyl chlorides of 4 to 6 carbon atoms in the tertiary alkyl group, especially N-vinyl-N-t-butylcarbamyl chloride.
REFERENCES:
patent: 3501523 (1970-03-01), Sayigh
patent: 3824280 (1974-07-01), Kiefer et al.
patent: 4001318 (1977-01-01), Botta
Breederveld. Rec. Trav. Chim. Pays-Bas 79, 1197-1202 (1960).
Kiefer Hans
Naarmann Herbert
BASF - Aktiengesellschaft
Love Ethel G.
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