Heteropolyacid catalyzed polymerization of olefins

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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5263487, 585510, 585527, 585530, C08F 422, C08F11010

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057102252

ABSTRACT:
Phosphotungstic acid salts are used to polymerize C.sub.2 -C.sub.30 .alpha.-olefins and derivatives thereof to form highly reactive products having a high content of terminal vinylidene groups and .beta.-isomers in resonance therewith. Isobutylene has been polymerized to form a Mn 300-20,000 polymer.

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