Production of branched arylene sulfide polymers

Chemistry of carbon compounds – Miscellaneous organic carbon compounds

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260 79, C08G 7516

Patent

active

040382613

ABSTRACT:
A method is provided for producing branched arylene sulfide polymers by contacting at least one p-dihalobenzene, at least one polyhalo aromatic compound having more than two halogen substituents per molecule, at least one alkali metal sulfide, at least one lithium carboxylate or lithium chloride, N-methyl-2-pyrrolidone, and at least one alkali metal hydroxide. The use of the polyhalo aromatic compound, which is employed in minor amounts, results in a polymer of reduced melt flow, which, without prior curing, can be molded, extruded, or spun into fibers.

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patent: 3607843 (1971-09-01), Vidaurri
patent: 3699087 (1972-10-01), Wood et al.
patent: 3725362 (1973-04-01), Walker
patent: 3763124 (1973-10-01), Edmonds, Jr.
patent: 3786035 (1974-01-01), Scoggin
patent: 3919177 (1975-11-01), Campbell

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