Production of p-phenylene sulfide polymers

Chemistry of carbon compounds – Miscellaneous organic carbon compounds

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260 79, C08G 7516

Patent

active

040382605

ABSTRACT:
A method is provided for producing p-phenylene sulfide polymers by contacting at least one p-dihalobenzene, at least one alkali metal sulfide, at least one organic amide and at least one alkali metal sulfonate at polymerization conditions. The use of an alkali metal sulfonate in addition to the other compounds contacted to form the reaction mixture results in a p-phenylene sulfide polymer of higher molecular weight than is produced without the alkali metal sulfonate, as evidenced by higher inherent viscosity and lower melt flow of the polymer than produced by the compared methods.

REFERENCES:
patent: 3607843 (1971-09-01), Vidaurri
patent: 3699087 (1972-10-01), Wood et al.
patent: 3725362 (1972-04-01), Walker
patent: 3763124 (1973-10-01), Edmonds, Jr.
patent: 3786035 (1974-01-01), Scoggin
patent: 3919177 (1975-11-01), Campbell

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