Esterification and extraction process

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260526R, 260528, 260531R, 260533C, 260535R, 260535P, 260536, 260537R, 260537P, 260537N, 260538, 260540, 260541, 560174, 560179, 560180, 560182, 560189, 560191, 560198, 560204, 560248, 560263, 560265, C07C 6748

Patent

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040827887

ABSTRACT:
Organic acids contained in aqueous solution are separated and/or recovered by a process comprising adding an alcohol to the aqueous solution to esterify the acids present, while preferably simultaneously contacting the alcoholic mixture with a water-immiscible solvent and separating layers into an aqueous phase and an organic phase, whereby extraction with the water-immiscible solvent shifts the equilibrium toward the formation of more esters. The esters of the acids may than be recovered as by distillation.

REFERENCES:
patent: 2824122 (1958-02-01), Kuceski
patent: 2968674 (1961-01-01), Franke et al.
patent: 3329712 (1967-07-01), Danly et al.

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