High modulus cholesteric mesophase polymers

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From phenol – phenol ether – or inorganic phenolate

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2642902, 356403, 427163, 428215, 428220, 428910, 525440, 525448, 525450, 528288, 528292, 528332, C08G 6936, C08G 6300

Patent

active

044120591

ABSTRACT:
A polymeric material which is capable of forming high modulus, biaxially orientable structures of a cholesteric mesophase, wherein said polymeric material comprises an optically active monomer which is condensation co-polymerized with at least one p-phenylene containing monomer which is itself capable of forming a polymer exhibiting a nematic mesophase, or which is capable of being copolymerized with a second monomer to form a nematic mesophase, or which is capable of being copolymerized with racemic mixture of said optically active monomers to form a nematic mesophase, wherein the resulting copolymer is characterized by a degree of inflexibility sufficient to form a mesophase and wherein said optically active monomer is present in said polymer after copolymerization in an amount sufficient to impart optical activity to said polymer sufficient to form a cholesteric mesophase.

REFERENCES:
patent: 2956987 (1960-10-01), Caldwell et al.
patent: 3352836 (1967-11-01), Schmitt et al.
patent: 3408334 (1968-10-01), Caldwell et al.
patent: 3671524 (1972-06-01), Suzuki
patent: 3991016 (1976-11-01), Morgan
patent: 4118372 (1978-10-01), Schaefgen
Macromolecules 10, No. 6, Nov./Dec. 1977, pp. 1401-1406, M. Panar et al.
CA 82 140624z, 112378d, 98631x.
CA 83 164632x, 179651b.
CA 84 106246j.

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