Process for the manufacture of unsaturated esters of carboxylic

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

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C07C 67055

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046688196

ABSTRACT:
Unsaturated esters of carboxylic acids are prepared by reacting olefines or cycloolefines with carboxylic acids and oxygen in the gaseous phase in the presence of a catalyst containing noble metal salts or noble metals of the VIII.sup.th group of the Periodic System and alcali metal salts and/or alcaline earth metal salts, as activators the content of noble metal being in the range of from 1.2 to 5% by weight and the proportion of the metal fraction of each individual activator to the noble metal content being in the range of from 0.5 to 1 to 3:1.

REFERENCES:
patent: 3546278 (1970-12-01), Haydon
patent: 3567767 (1971-03-01), Yasui
patent: 3625998 (1971-12-01), Fernholz
patent: 3634496 (1972-01-01), Kominami
patent: 3658888 (1972-04-01), Hornig
patent: 3670014 (1972-06-01), Fernholz
patent: 3759839 (1973-09-01), Fernholz
patent: 3761513 (1973-09-01), Sennewald
patent: 3847972 (1974-11-01), Kominami
patent: 3917676 (1975-11-01), Kasaki
patent: 3939199 (1976-02-01), Fernholz
patent: 3950400 (1976-04-01), Fernholz
Moisejev et al Doklady Akademii Nauk, vol. 133, No. 2, pp. 377-380 (1960).

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