Process for the preparation of aminoacetic acids with a tertiary

Details Process for the preparation of aminoacetic acids with a tertiary Process for the preparation of aminoacetic acids with a tertiary

1997-06-10

1998-11-03

McKane, Joseph K.

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acids and salts thereof

562575, C07C22900

Patent

active

058311190

ABSTRACT:
A process for the preparation of aminoacetic acids or aminoacetonitriles with a tertiary hydrocarbon radical in the .alpha.-position in which monoamide derivatives of malonic acid are subjected to a Hofmann rearrangement.

REFERENCES:
J. March, Advanced Organic chemistry, Reactions, Mechanims, and Structure, 4th ed., pp. 1090-1091, 1992.
Toshifumi Miyazawa, et al., No. 23, pp. 51-54, "Synthesis of T-Leucine", May 31, 1979.

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