Process for preparing azasulfonium halide salts

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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26029373, 2602948D, 2602948E, 260296R, 260325R, 26032612R, 26032616, 26032655, 260329AM, 2603407, 2603409, 260465E, 260470, 260481R, 260551S, 260578, C07D20946, C07D20908

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039547973

ABSTRACT:
Preparing azasulfonium halide salt derivatives of an aniline by reacting a halogen with a non-carbonylic dihydrocarbon sulfide, a beta-carbonylic hydrocarbon sulfide, or a .beta.-thio ester or amide to form a halogen: sulfur compound complex and then reacting the complex with an aniline to form the azasulfonium halide salts. The azasulfonium halide salts are useful as intermediates in processes for making ortho-alkylated anilines, indoles, and 2-oxindoles which have a variety of known uses.

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