Cyclic polyester oligomer polymerization

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From carboxylic acid or derivative thereof

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528176, 528182, 528190, 528272, 528274, 528279, 528298, 528355, 528370, 528371, 549264, 549267, 549268, 549269, C08G 6300

Patent

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047571322

ABSTRACT:
Cyclic polyester and especially polyarylate oligomers, typically having degrees of polymerization from 2 to about 7, are prepared by reacting a bisphenol such as bisphenol A or 6,6'-dihydroxy-3,3,3',3'-tetramethylspiro(bis)indane with a dicarboxylic acid chloride such as isophthaloyl or terephthaloyl chloride in the presence of a catalyst, under conditions of low concentration. The cyclic oligomers may be polymerized to linear polyesters by contact with a transesterification catalyst at a temperature in the range of about 200.degree.-300.degree. C.

REFERENCES:
Wick et al., Angew. Makromol. Chem., 112, 59-94, (1983).

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