Preparation of 9-BBN

Details Preparation of 9-BBN Preparation of 9-BBN

1973-11-08

1976-10-05

Sneed, Helen M. S.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

C07F 502

Patent

active

039844790

ABSTRACT:
9-Borabicyclo (3.3.1) noname (9-BBN), a relatively stable solid dialkylborane, can be used to reduce a wide variety of reducible chemical compounds, including both organic and inorganic compounds. The stability of the reagent greatly reduces the operating difficulties encountered with other dialkylboranes having similar reduction properties, which are thermally and hydrolytically unstable.

REFERENCES:
patent: 2925437 (1960-02-01), Brown
patent: 2925438 (1960-02-01), Brown
patent: 3155732 (1964-11-01), Lang et al.
patent: 3157704 (1964-11-01), Salgebarth
patent: 3180894 (1965-04-01), Lang et al.
J.A.C.S v. 90 pp. 5280-5284 (1968).
J.A.C.S v. 81, pp. 6428-6437 (1959).
Chemistry & Industry, pp. 2087-2088 (1962).

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