Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...
Patent
1971-10-18
1976-10-05
Smith, Edward J.
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
Polymers from only ethylenic monomers or processes of...
252429C, 526352, C08F 402, C08F 1002
Patent
active
039843890
ABSTRACT:
This invention relates to the polymerization of .alpha.-olefins and to catalysts and to cocatalysts for that purpose wherein the polymerization is carried out in the presence of a catalyst comprising an organometallic compound of a metal of Groups IA, IIA, IIB, IIIA, and IVA of the Periodic Table and a cocatalyst comprising a reaction product of a halogenated derivative of a transition metal of Groups IVB, VB, and VIB of the Periodic Table and a hydrous divalent metal salt of a carboxylic acid, the cocatalyst having a gram equivalent ratio of halogen/divalent metal plus transition metal greater than 0.5. The invention also comprises the method of making the cocatalysts.
REFERENCES:
patent: 3676415 (1972-07-01), Diedrich et al.
patent: 3694421 (1972-09-01), Vetter
Delbouille Andre
Derroitte Jean-Louis
Smith Edward J.
Solvay & Cie
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