Process for preparing a methylenebis(2-hydroxy-4-alkoxybenzophen

Chemistry of carbon compounds – Miscellaneous organic carbon compounds

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260 23H, 252404, 260 4585R, 260591, 560255, C08K 513, C07C 4500, C07C 6928, C07C 6916

Patent

active

041894090

ABSTRACT:
A novel process is provided for preparing a methylenebis(2-hydroxy-4-alkoxybenzophenone), comprising forming a novel 2-hydroxy-4-alkoxyacyloxymethylbenzophenone by a reaction of a 2-hydroxy-4-alkoxybenzophenone with a carboxylic acid and formaldehyde, and causing the 2-hydroxy-4-alkoxyacyloxymethylbenzophenone to react with a 2-hydroxy-4-alkoxybenzophenone in the presence of an acid catalyst.
Both the acyloxymethylhydroxyalkoxybenzophenone and methylenebis(2-hydroxy-4-alkoxybenxophenone) which are prepared according to this invention are useful to prevent-degradation of organic materials, particularly as light stabilizers for synthetic resins.

REFERENCES:
patent: 3086988 (1963-04-01), Gordon
patent: 3317462 (1967-05-01), Goldberg et al.
patent: 3399237 (1968-08-01), Dressler et al.
CA-67, 1967, 32417 r.

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