Polymerization process using bisquinone peroxide catalyst

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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525273, 524340, 526208, 5262325, C08F 434, C08F27902, C08F29102

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048959073

ABSTRACT:
An improved free radical polymerization process employing as a polymerization initiator a bisquinone peroxide. Upon decomposition to initiate polymerization such bisquinone peroxides may also produce singlet oxygen capable of producing hydroperoxidized rubber if rubber is included in the polymerization mixture. The by-products formed from the decomposition of the bisquinone peroxide desirably comprise hindered phenolic compounds having antioxidant properties.

REFERENCES:
patent: 4054615 (1977-10-01), Hardt et al.
Chem. Abst. 87 (6): 39905v, Ryabov, A. V., Polymerization of Styrene . . . (1976) (USSR).

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