Process for the preparation of 2-aryl-2H-benzotriazoles

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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548259, C07D24920

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active

042244510

ABSTRACT:
A two stage reductive ring closure of o-nitrophenylazophenols produces 2-aryl-2H-benzotriazoles by (a) reacting an organic solvent solution of azophenol with an excess of an aqueous solution of a sulfhydrate or sulfide to form an N-oxide and (b) reducing the N-oxide with an alkali metal hydroxide plus zinc or tin.

REFERENCES:
patent: 2362988 (1944-11-01), Conzetti et al.
patent: 4001266 (1977-01-01), Rody et al.

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