Hydrocarbon oxidations catalyzed by nitride-activated metal coor

Details Hydrocarbon oxidations catalyzed by nitride-activated metal coor Hydrocarbon oxidations catalyzed by nitride-activated metal coor

1987-01-02

1990-01-23

Lone, Werren B.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260413, 560241, 5602411, 5625122, 562549, 5683988, 568399, 568910, 5689105, C07C 6700, C07C 2712, C07C 4532, C07C 4533

Patent

active

048956805

ABSTRACT:
Hydrocarbon, and particularly lower molecular weight alkanes and cycloalkanes, may readily be oxidized with air or O.sub.2 to form such products as alcohols, ketones, and the like in high yields when there is employed as the catalyst a highly active nitride-activated metal coordination complex having the structure ##STR1## where M is a transition metal; " " is a ligand; and X is a nitride. Certain dimeric forms of the above catalyst are also employed herein. It has also been discovered that Group IV through VIII transition metal nitrides are also highly effective oxidation catalysts for lower molecular weight hydrocarbons such as alkanes.

REFERENCES:
patent: 3816548 (1974-06-01), Williams et al.
patent: 3873625 (1975-03-01), Barone
patent: 4028423 (1977-06-01), Brownstein et al.
patent: 4459427 (1984-07-01), Middleton et al.
J. E. Lyons, Hydrocarbon Processing, Nov. 1980, p. 107, Table I.
Taylor et al., J. Chem. Soc. Chem. Comm. 279 (1984).
Mansuy et al., ibid., 253 (1983).
Groves et al., J. Am. Chem. Soc., 102, 6377 (1980).
Hill et al., ibid., 102, 6374, (1980).
Smegal et al., ibid., 105, 5515, (1983).
Tabushi et al., ibid., 103, 7371, (1981).

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