Olefin oxidation process

Details Olefin oxidation process Olefin oxidation process

1977-06-29

1979-05-01

Thomas, Jr., James O.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260586P, 260604R, C07C 4504

Patent

active

041523547

ABSTRACT:
Olefins are oxidized to carbonyl compounds, for example, 1-hexene to 2-hexanone, with a Pd/Cu/alkali metal or alkaline earth metal chloride catalyst and a suitable surfactant in a diluent system comprising at least two liquid phases, wherein at least one liquid phase is an aqueous phase, in the presence of free oxygen. The addition of the surfactant to the system provides an improvement in olefin conversion and selectivity to the corresponding carbonyl compound. Suitable surfactants include, for example, quaternary ammonium halide compounds.

REFERENCES:
patent: 3154586 (1964-10-01), Bender

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