Polyvinyl alcohol cross-linked with two aldehydes

Details Polyvinyl alcohol cross-linked with two aldehydes Polyvinyl alcohol cross-linked with two aldehydes

1981-06-10

1982-11-02

Levin, Stanford M.

Chemistry: electrical current producing apparatus, product, and

Current producing cell, elements, subcombinations and...

Include electrolyte chemically specified and method

264104, 429253, 525 61, C08F 828, H01M 200, H01M 216, H01M 218

Patent

active

043574025

ABSTRACT:
A film-forming polyvinyl alcohol resin is admixed, in aqueous solution, with a dialdehyde cross-linking agent which is capable of cross-linking the polyvinyl alcohol resin and a water soluble acid aldehyde containing a reactive aldehyde group capable of reacting with hydroxyl groups in the polyvinyl alcohol resin and an ionizable acid hydrogen atom. The dialdehyde is present in an amount sufficient to react with from 1 to 20% by weight of the theoretical amount required to react with all of the hydroxyl groups of the polyvinyl alcohol. The amount of acid aldehyde is from 1 to 50% by weight, same basis, and is sufficient to reduce the pH of the aqueous admixture to 5 or less. The admixture is then formed into a desired physical shape, such as by casting a sheet or film, and the shaped material is then heated to simultaneously dry and cross-link the article.

REFERENCES:
patent: 4272470 (1981-06-01), Hsu et al.

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