Preparation of imides

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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546200, 546201, 546208, 548539, 560 97, 560206, 562406, C07D20948

Patent

active

049334662

ABSTRACT:
Cyclic imides are prepared by reacting carbon monoxide with an ortho dihalide aromatic compound or a cis-1,2-vinyl dihalide and an amine in the presence of palladium catalyst and a base. The process is preferably conducted in the presence of a dipolar aprotic solvent as a liquid reaction medium.
Acyclic imides are prepared by reacting CO with an activated halide and an amide (primary or secondary) in the presence of a Pd catalyst and a base.

REFERENCES:
patent: 3988358 (1976-10-01), Heck
patent: 4761499 (1988-08-01), Epstein

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