Chemistry: fischer-tropsch processes; or purification or recover – Liquid phase fischer-tropsch reaction
Patent
1986-05-13
1987-06-02
Mars, Howard T.
Chemistry: fischer-tropsch processes; or purification or recover
Liquid phase fischer-tropsch reaction
518715, 518721, C07C 104
Patent
active
046704728
ABSTRACT:
A Fischer-Tropsch process utilizing a product selective and stable catalyst by which synthesis gas, particularly carbon-monoxide rich synthesis gas is selectively converted to higher hydrocarbons of relatively narrow carbon number range is disclosed. In general, the selective and notably stable catalyst, consist of an inert carrier first treated with a Group IV B metal compound (such as zirconium or titanium), preferably an alkoxide compound, and subsequently treated with an organic compound of a Fischer-Tropsch metal catalyst, such as cobalt, iron or ruthenium carbonyl. Reactions with air and water and calcination are specifically avoided in the catalyst preparation procedure.
REFERENCES:
patent: 4499209 (1985-02-01), Hock et al.
patent: 4605680 (1986-08-01), Beuther et al.
Dyer Paul N.
Pierantozzi Ronald
Withers Howard P.
Air Products and Chemicals Inc.
Innis E. Eugene
Jones, II Will
Mars Howard T.
Simmons James C.
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