Preparation of alkanes substituted by chlorine atoms and/or sulf

Chemistry: electrical and wave energy – Processes and products – Electrostatic field or electrical discharge

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204163R, B01J 110

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active

042421870

ABSTRACT:
Alkanes substituted by chlorine atoms and/or sulfochloride groups are prepared by reacting alkanes with chlorine, with or without sulfur dioxide, in a particular throughput ratio, in a reaction chamber inclined to the horizontal, the starting materials being passed through the reaction chamber in co-current, from below. The substituted alkanes or paraffins obtainable by the process of the invention are pesticides, plasticizers, solvents and starting materials for the preparation of such products, as well as of fat liquors, detergents, lubricating oils, synthetic resins and slip agents.

REFERENCES:
patent: 3402114 (1968-09-01), Hutson, Jr. et al.
patent: 3911004 (1975-10-01), Hertel et al.
Ullmanns Encyclopadie der Technischen Chemie, vol. 5 (1954) pp. 435, 437, 438 and 448.
Ullmanns Encyclopadie der Technischen Chemie, vol. 8 (1957) pp. 353 to 356.
Ullmans Encyclopadie der Technischen Chemie, vol. 16 (1965) pp. 562 and 563.
Lindner, Tenside-Textilhilfsmittel-Waschrohstoffe, 2nd Ed., vol. 1, pp. 708 to 713 (1964).

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