Liquid/liquid extraction/purification of impure solutions of rar

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Rare earth metal

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423157, 423DIG14, 210634, 210643, 210644, B01D 1104

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047269383

ABSTRACT:
Aqueous nitric solutions of salts of at least one rare earth, and containing contaminating amounts of at least one alkaline earth cation, e.g., calcium, barium and/or radium, are conveniently purified by liquid/liquid extracting same with an organic phase which comprises a polyether extractant for said at least one alkaline earth cation, e.g., a crown ether, and whereby said at least one alkaline earth cation is selectively transferred into said organic phase.

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