Process for preventing the extraction of technetium and/or rheni

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Radioactive metal

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252626, 252627, 252631, 423 3, 423 8, 423 215, 423 49, 423 70, 210682, B01D 1100, G21C 1946, G21C 1950, G21F 904

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active

047643528

ABSTRACT:
Process for preventing the extraction of technetium and/or rhenium, particularly during the extraction of uranium and/or plutonium by an organic solvent.
This process permitting the extraction of a chemical element, such as uranium or plutonium present in an aqueous solution containing both said element, technetium and/or rhenium and zirconium and/or hafnium consists of contacting the aqueous solution with an organic solvent able to extract said element, wherein for preventing the extraction of the technetium and/or rhenium with said element, to the aqueous solution is added a zirconium and/or hafnium complexing agent in a quantity adequate for complexing all the zirconium and/or hafnium, said agent being soluble in the aqueous solution.

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Wilson, et al. 1984, The impact of technetium on reprocessing chemistry, Intl. Meeting on Fuel Reprocessing & Waste Mgmt. Jackson Hole, Wyoming, 10 pages.
Vandegrift et al. 1984, Transuranic decontamination of nitric acid solutions by the truex solvent extraction process, Argonne Nat'l Lab. pp. 1, 45-50, 107-110.
Garraway et al. 1984, the technetium catalysed oxidation of hydrazine by nitric acid, Journal of Less Common Metals 97: 191-203.

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