Multi-component ethylenically unsaturated peroxyesters

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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528272, 528274, 528306, 525437, 526203, 526228, 526230, 526323, 526335, 522 24, 522 28, 522 60, 522 63, 522 65, 522 67, 522 68, 522 71, 522 93, 522102, 522104, C08F 2000

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056440049

ABSTRACT:
A novel and safe ethylenically unsaturated peroxyester composition derived from an ethylenically unsaturated dicarboxylic acid is provided, as well as processes for making and using the composition. The peroxyester composition comprises about 0.04 to about 0.70 mole fraction of a first component compound having a formula I: ##STR1## about 0.32 to about 0.50 mole fraction of a second component compound having a formula II: ##STR2## about 0.04 to about 0.70 mole fraction of a third component compound having a formula III: ##STR3## wherein Q is an unsaturated ethylene divalent radical and R.sup.1 and R.sup.2 are organic substituents. Polymeric-peroxides are prepared via polymerizing the peroxyester compositions. The peroxyester compositions are also used for curing unsaturated polyester resins and for initiating polymerization of ethylenically unsaturated monomers.

REFERENCES:
patent: 3536676 (1970-10-01), Mageli et al.
patent: 3763112 (1973-10-01), Bafford et al.
Visn, L'viv. Politekh, Inst., 1974, 82,24-7 (Translation and Original).
Chem. Abs., 105, (20): 17323Ls (1986)--Abstracting Japanese Patent Appln. 84/209679.

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