Chemistry: electrical and wave energy – Processes and products
Patent
1987-11-09
1988-07-19
Andrews, R. L.
Chemistry: electrical and wave energy
Processes and products
C25C 100
Patent
active
047583150
ABSTRACT:
The process according to the invention is a process for the electrosynthesis of teritary arylalkylphosphines by electrochemical reduction of arylhalophosphines in the presence of aliphatic halides, in an organic solvent medium.
The anode, made of a reducing metal such as zinc, aluminum or magnesium, is sacrificed during the electrosynthesis.
The cell is preferably non-compartmented.
The process is simple and inexpensive.
Teritary arylalkylphosphines are compounds which are widely used in homogeneous catalytic systems.
REFERENCES:
patent: 4655883 (1987-04-01), Farnung
patent: 4689123 (1987-08-01), Noding
Folest Jean-Claude
Perichon Jacques
Andrews R. L.
Societe Nationale des Poudres et Explosifs
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