Polynitroethylthionocarbonates and method of preparation

Details Polynitroethylthionocarbonates and method of preparation Polynitroethylthionocarbonates and method of preparation

1981-02-17

1982-04-06

Jiles, Henry R.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

C07C15400

Patent

active

043235182

ABSTRACT:
Bis(2,2-dinitropropyl)thionocarbonate, [CH.sub.3 C(NO.sub.2).sub.2 CH.sub.2 ].sub.2 C.dbd.S; bis(2,2,2-trinitroethyl)thionocarbonate, [C(NO.sub.2).sub.3 CH.sub.2 O].sub.2 C.dbd.S; and bis(2,2-difluoro-2-nitroethyl)thionocarbonate, [CF.sub.2 (NO.sub.2)CH.sub.2 O].sub.2 C.dbd.S are prepared by reacting one mole of 1,1'-thiocarbonyldi-1,2,4-triazole with 2 moles of 2,2-dinitropropanol, 2,2,2-trinitroethanol, or 2,2-difluoro-2-nitroethanol, respectively. These compounds are useful as explosives and as intermediates for the preparation of energetic explosives and plasticizers.

REFERENCES:
patent: 3694482 (1972-09-01), Engelhart

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