Synthesis of acetyl-T-alkanes

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568388, C07C 4565

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active

043980449

ABSTRACT:
Acetyl-tertiary-alkanes are prepared by hydrolytic decarboxylation of tertiary-alkanoylacetonitriles with hydrochloric acid.

REFERENCES:
patent: 3609192 (1971-09-01), Hoffman et al.
House, Modern Synthetic Rxns., pp. 511-513, 552-555 & 624, (1972).
Vigier et al., Chem. Abst., vol. 57, #9798h, (1962).
Robertson et al., Chem Abst., vol. 25, #3324.sup.8, (1931).
House and Larson, J. Org. Chem. 33, 61-65, (1968).
Corey and Durst, J. Am. Chem. Soc. 90, 5548-5552, (1968).
Oishi et al., Chem. Pharm. Bull. 17, 2314-2318, (1969).

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