Hydroxyfluoroalkyl-substituted styrenes and polymeric compositio

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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525426, 525445, C08F25908

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active

053527429

ABSTRACT:
Fluorinated styrenes of the formula I: ##STR1## where R.sub.1 is a C.sub.1 -C.sub.6 alkyl and R.sub.2 is the repeating unit ##STR2## where x is zero or any positive integer, which are useful as compatibilizing and toughening agents for various polymers such as styrene, dienes (butadiene, isoprene, etc.) acrylates, polymethacrylates, polycarbonates, polyesters, polyamides, etc. Particularly preferred are p-(1,1,1,3,3,3-hexafluoro-2-hydroxy isopropyl)-.alpha.-methylstyrene, polymers thereof, block and random copolymers thereof and polymer blends incorporating the same.

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Journal of Macromolecular Science-Chemistry, A21, pp. 1181-1216 (1954), Pce, et al "Polymer Compatibilization through hydrogen bonding".
Macromolecules, vol. 24, No. 2, 464-473, 1991, Han et al, "Spinodal decomposition in a hydrogen-bonded polymer blend."
CA 114(22):208303f--Ming et al. Makromol. Chem. Macromol. Symp., 38 (Invited Lect. Microsymp. Makromol. Polym. Blends 32nd., 1989) 161-72-1990.

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