PVC coatings for electrodes

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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525104, C08L 2722

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active

052832880

ABSTRACT:
This invention involved the discovery of novel polymers and a process for their preparation. The polymers were prepared by the nucleophilic substitution, at room temperature, of PVC with substituted alkyltrialkoxysilanes, which can be cured at room temperature to give adhesion of PVC to hydrophilic substrates. These polymers are particularly useful as adhesion promoters in ion-selective electrodes. The invention also involved the application of these adhesive primers to planar electrode substrates to give greatly improved performance in the response of ion-selective electrodes.

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Ma, S. C. et al, Response Properties of Ion-Selective Polymeric Membrane Electrodes Prepared with Animated and Carboxylated Poly (vinyl chloride), Anal. Chem., 60 (1988) 2293.
Moody, G. J. et al, Modified Poly (vinyl chloride) Matrix Membranes for Ion-selective Field Effect Transistor Sensors, Analyst 113 (1988) 1703.
Morrall, S. W. et al, Modification of Siliceous Surfaces with Alkoxysilanes from a Nonaqueous Solvent, in "Silanes, Surfaces, and Interfaces", Ed. by D. E. Leyden (1986), p. 501.
Satchwill, T. et al, Synthesis and Characterization of New Polyvinylchloride Membranes for Enhanced Adhesion on Electrode Surfaces, J. Electroanal. Chem. 2020 (1986) 75.

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