Process for producing fluorinated acid fluoride having ester gro

Details Process for producing fluorinated acid fluoride having ester gro Process for producing fluorinated acid fluoride having ester gro

1980-02-14

1985-01-22

Trousof, Natalie

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

560184, C07C 6714

Patent

active

044953640

ABSTRACT:
A fluorinated acid fluoride having an ester group which has the formula ##STR1## wherein A,p, q and R are defined below is produced by reacting a diacid fluoride having the formula ##STR2## wherein A represents a C.sub.1 -C.sub.10 bifunctional perfluoro group; p represents 0 or 1; q represents an integer of 1 to 8 with an alcohol having the formula ROH wherein R represents an organic group.

REFERENCES:
patent: Re29534 (1978-02-01), Resnick
patent: 3250807 (1966-05-01), Fritz et al.
March, Jerry, Advanced Organic Chemistry, 2nd Ed., (1980) McGraw-Hill Publ., pp. 17-19, 320 and 803.
Groggins, P. H. "Unit Processes in Organic Synthesis" McGraw-Hill, Publ. 5th Ed., (1958), at p. 698.
Cason, James et al., J. Org. Chem. (1961), pp. 2024-2026, vol. 26.
House, Herbert O. "Modern Synthetic Reactions" W. A. Benjamin, Publ. 2nd. Ed., (1972), p. 302.
Tarrant, Paul "Fluorine Chemistry Reviews" Marcel Dekker, Publ., (1971), vol. 5, pp. 87, 90, and 95.
Malinovskii, M. S. "Epoxides and Their Derivatives" Israel Program for Scientific Translations, Publ., (1965), pp. 109, 123 and 158.
Kirk-Othmer "Encyclopedia of Chemical Technology" Interscience, Publ. 2nd Ed., (1969), vol. 16, p. 597.
Pauling, Linus "The Nature of the Chemical Bond" Cornell Univ. Press, Publ., (1948), pp. 64-67.

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