Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1979-06-06
1980-09-16
Demers, Arthur P.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
260561R, C07C10200, C07C10334
Patent
active
042229596
ABSTRACT:
A process for the preparation of aromatic formamides by reacting an aromatic amine with carbon monoxide in the presence of a solvent, a catalytic quantity of a copper salt and oxygen, or an oxygen-containing gaseous mixture. The reaction is preferably carried out in the presence of excess amine, a volatile alcohol solvent, and a copper halide catalyst.
REFERENCES:
patent: 2793211 (1957-05-01), LoCicero
patent: 3099689 (1963-07-01), Cragg
patent: 3530182 (1970-09-01), Haines
Beckwith, The Chemistry of Amides, Interscience Publishers N.Y., N.Y., 1970, p. 118.
Saegusa et al., Tet. Letters, 1966, #49, pp. 6125-6129.
Saegusa et al., Bull. Chem. Soc., Japan, 42 (1969), pp. 2610-2614.
Nefedov et al., Izv. Akad. Nauk., SSUR, Ser Khim, #7, (1973), pp. 1536-1540.
Atlantic Richfield Company
Demers Arthur P.
Reap Coleman R.
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