Process for the continuous production of monochloroalkanes

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260648C, 260657, C07C 1716, C07C 2310

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active

040738167

ABSTRACT:
Monochloroalkanes are produced by reacting the corresponding alcohol with hydrogen chloride in the presence of a solution of zinc chloride. The mixture of alcohol and zinc chloride solution is saturated with gaseous hydrogen chloride and this mixture in a thin layer contacted with gaseous hydrogen chloride.

REFERENCES:
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patent: 2026131 (1935-12-01), Klein et al.
patent: 2124605 (1938-07-01), Bousquet
patent: 2396639 (1946-03-01), Carter
patent: 2622107 (1952-12-01), Mattson
patent: 2847484 (1958-08-01), Kolker
patent: 3502733 (1970-03-01), Kurtz et al.
Meyer-Jacobson, "Lehrbuch der Organischen Chemie" Zweite Auflage, Erster Band, Allgemeiner Teil, Erster Teil, Leipzig (1907), p. 281.

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