Process for preparing a niobium activated yttrium tantalate X-ra

Compositions – Inorganic luminescent compositions – Compositions containing halogen; e.g. – halides and oxyhalides

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C09K 1178

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active

049293869

ABSTRACT:
A process is disclosed for preparing a single phase M'YTaO.sub.4 :Nb X-ray phosphor which comprises firing a uniform milled mixture consisting essentially of the components of Y.sub.2 O.sub.3, Ta.sub.2 O.sub.5, and Nb.sub.2 O.sub.5 in an amount equal to the stoichiometric amounts to form the phosphor, with a flux consisting essentially of lithium sulfate and potassium sulfate in a mole ratio of about 80 to 20, wherein the flux makes up from about 25% to about 50% by weight of the mixture. The firing is done by heating in a furnace to a temperature of from about 1200.degree. C. to about 1300.degree. C. at a heating rate of from about 1.0.degree. C. per minute to about 1.5.degree. C. per minute and maintaining the temperature for about 10 to 14 hours to react the components and produce a fired material containing luminescent material. The material is cooled by turning off the heat to the furnace and allowing the fired material to remain in the furnace until the temperature in the furnace is no higher than about 300.degree. C. The material is washed, dried, and classified to obtain a -325 mesh particle size. The phosphor essentially free of the impurity phases of Y.sub.3 TaO.sub.7, the freedom from the impurity phases resulting in an improvement in brightness over phosphors produced by prior methods and having the impurity phases present.

REFERENCES:
patent: 3459674 (1969-08-01), Emoto et al.
patent: 4024069 (1977-05-01), Larach
patent: 4225653 (1980-09-01), Brixner
"On the Structural and Luminescent Properties of the M'LnTaO.sub.4 Rare Earth Tantalates", Brixner & Chen, Electrochem. Soc. 130 (12), 1983, 2435-43.

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