Process for the preparation of carboxylic acids and N-tert.-alky

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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546319, 562400, 562490, 562492, 562493, 562495, 562496, 562606, 564 1, 564336, 564462, 564488, C07D21190, C07D 53134

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044967365

ABSTRACT:
Carboxylic acids and N-t.-alkylamines can be prepared simultaneously by the alkaline pressure hydrolysis of N-t.-alkyl carboxylic acid amides. A 5 to 50% strength by weight aqueous solution of an alkali metal hydroxide is employed for this purpose in an amount of 1.0 to 1.3 mols per mol of the amide. The process is carried out at 200.degree. to 350.degree. C.

REFERENCES:
patent: 3898280 (1975-08-01), Pander
Hutchison et al., Australian J. of Chem. 18(5), pp. 699-706, (1965).
Ritter et al., J. A. C S., vol. 70, (1948), pp. 4045-4050.

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