Method for preparing functional alpha-olefin polymers and copoly

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526239, 5253266, 525337, 525351, 525369, C08F 464, C08F 3006, C08F 3000

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047512768

ABSTRACT:
The present invention relates to a process for the preparation of functional alpha-olefin homo- and copolymers by polymerization through a borane monomer intermediate.
Borane monomers, derived from mono-hydroboration of appropriate dienes with dialkyl borane, have been found to be stable to Ziegler-Natta catalysts. In turn, the borane homo- and copolymers are easily converted to a variety of other functionalities; e.g., alcohols, aldehydes, amines, etc.

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"Recent Developments in Chemical Modifications of Polydienes" Pirrazzi et al., Appl. Polyn. Symp. No. 26, pp. 73-98, 1975.

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