Process for the removal of lead and cadmium from phosphoric acid

Chemistry of inorganic compounds – Phosphorus or compound thereof – Oxygen containing

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C01B 2516

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active

054318955

ABSTRACT:
To remove lead and cadmium from phosphoric acid, alkali solution and aqueous sulfide solution are simultaneously introduced with thorough mixing into a phosphoric acid having a P.sub.2 O.sub.5 content of up to 32% by weight, an iron content of up to 0.3% by weight and an alkali/P ratio of up to 0.30. The temperature of the phosphoric acid which is thoroughly mixed with alkali solution and sulfide solution is adjusted to temperatures of 58.degree. to 72.degree. C. with escape of the excess hydrogen sulfide. To complete the sulfide precipitation, the temperature is lowered to below 45.degree. C. Finally, the precipitated sulfides of the lead and cadmium are separated off from the phosphoric acid.

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patent: 4670244 (1987-06-01), Roos et al.
patent: 4769226 (1988-09-01), Winand et al.
patent: 4777028 (1988-10-01), Schrodter

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