Isomerization of 2-pentenoates to 3-pentenoates

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

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562499, C07C 6952, C07C 67293

Patent

active

049067699

ABSTRACT:
3-pentenoates are prepared by isomerization of 2-pentenoates to 3-pentenoates by a process in which the 2-pentenoate is treated with from 0.01 to 0.5 mole of cyclic tertiary amine having a pK.sub.a of >6 per mold of 2-pentenoate at from 50.degree. to 250.degree. C. and the 3-pentenoate is distilled off continuously.

REFERENCES:
patent: 4327225 (1982-04-01), Isogai et al.
patent: 4788326 (1988-11-01), Hoelderith
patent: 4791220 (1988-12-01), Fischer

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