Direct catalytic synthesis of dimethyldichlorosilane from methyl

Organic compounds -- part of the class 532-570 series – Organic compounds – Silicon containing

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502244, C07F 716

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active

046616136

ABSTRACT:
Dimethyldichlorosilane is directly prepared from methyl chloride and silicon, in high productivity, selectivity and degree of silicon conversion, by reacting methyl chloride with a solid contact mass comprising silicon and a catalytically effective amount of a catalyst which includes (1) elemental copper or a copper compound, (2) from about 30 to 1,000 ppm (calculated as metallic tin and/or antimony) of at least one of the metals tin and antimony, or at least one compound of at least one of the metals tin and antimony, and (3) from about 0.05 to 4% by weight, (calculated as cesium metal) of cesium or a cesium compound, or admixture of cesium with up to 90% by weight of the admixture of lithium, sodium, potassium or rubidium, the amounts of said components (2) and (3) being based upon the total weight of said solid contact mass.

REFERENCES:
patent: 2380995 (1945-08-01), Rochow
patent: 2889350 (1959-06-01), Horny et al.
patent: 2917529 (1959-12-01), Drysdale
patent: 3155698 (1964-11-01), Nitzsche et al.
patent: 3555064 (1971-01-01), Turetskaya et al.
patent: 4170570 (1979-10-01), Zagata et al.

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