Two component polyurethane system for casting expanded polytetra

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From silicon reactant having at least one...

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4273935, 4283066, 4283084, 528 48, 528 76, 528 77, 528 83, 528 58, C08G 1861

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048144126

ABSTRACT:
The present invention provides a two component polyurethane system with excellent wetting properties for casting a supported or unsupported, expanded polytetrafluoroethylene structure. It consists essentially of a polyisocyanate component having an isocyanate functionality of 2.2 or less and a polyol blend having an overall hydroxyl functionality of 2.2 or less and a viscosity of less than 500 cps., preferably 200 cps. or less. The polyol blend consists essentially of (i) a linear polyether or polyester (about 200-2500 molecular weight), (ii) a diol or triol (less than 200 molecular weight), and (iii) a catalyst in an amount sufficient to provide gelling at greater than 2 minutes and less than 10 minutes. The isocyanate to hydroxyl ratio is between 0.95:1 and 1.10:1. In some cases, it is desirable to include selected siloxane surfactants when polyol blends with the higher viscosities, i.e., about 200-500 cps., are used. The casting system is useful for making membrane filters.

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