Process for the preparation of 1,4-diamino-2,3-dicyanoanthraquin

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260378, C07C143665, C07C 9724

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active

046612920

ABSTRACT:
The invention relates to a process for the preparation of 1,4-diamino-2,3-dicyanoanthraquinone, starting from 1,4-diaminoanthraquinones, or salts thereof, of the formula ##STR1## wherein n is 0, 1 or 2. To introduce the two cyanide radicals, the starting material is treated, in the presence of an oxidizing agent, with a compound which donates cyanide ions. The process comprises using as solvent a mixture of a carboxamide, an N-alkylated carboxamide or a lactam and water, which mixture contains more than 10% by weight of water.
1,4-Diamino-2,3-dicyanoanthraquinone is an important intermediate for the synthesis of textile dyes.

REFERENCES:
patent: 4294769 (1981-10-01), Krock et al.
patent: 4299771 (1981-11-01), Takeshita et al.
patent: 4422973 (1983-12-01), Krock et al.

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