Acrylate ester ether derivatives

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526318, 5263182, 526322, 5263231, 526304, 526312, 526316, 526266, 526270, C08F 2004

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active

049994107

ABSTRACT:
A process for synthesizing ethers of alkyl alpha-(hydroxymethyl)-acrylate by reacting alkyl acrylate and formaldehyde in the presence of a DABCO catalyst. The ethers may be used as cross-linking agents for thermoplastic polymers. Further, these ethers in turn enable synthesis of cyclopolymers that may show promising biological activity.

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Amri et al., Hydroxyalkylation De La Methylvinylcetone et De L'Acrylonitrile en Presence de Diaza-1, 4 Bicyclo [2.2.2] Octane, 27 Tetrahedron Letters, pp. 4307-4308 (1986).
Villieras et al, Wittig-Horner Reaction in Heterogeneous Media; 1. An Easy Synthesis of Ethyl .alpha.-Hydroxymethylacrylate and Ethyl .alpha.-Halomethylacrylates Using Formaldehyde in Water, Synthesis, pp. 924-926 (1982).

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