Production of allyl chloride

Organic compounds -- part of the class 532-570 series – Organic compounds – Halogen containing

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Details

570220, 570224, 570225, 570223, 570231, 570234, C07C 1702, C07C 1734, C07C 1715

Patent

active

048990000

ABSTRACT:
A process is provided for the production of allyl chloride from three carbon atom hydrocarbons (propane and/or propylene) using hydrogen chloride or hydrogen chloride/chlorine mixtures as the chlorinating agent. The process includes reaction steps operated in tandem in separate zones first comprising the reaction of perchloroethylene with hydrogen chloride and oxygen in the presence of an oxychlorination catalyst to give hexachloroethane and water, second comprising the vapor phase reaction of hexachloroethane with propane/propylene feedstock to produce allyl chloride, perchloroethylene, and hydrogen chloride, and third isolating the products of the second step and repeating the first step using as starting materials the thus isolated perchloroethylene and hydrogen chloride.

REFERENCES:
patent: 2447410 (1948-08-01), Hampel
patent: 3449450 (1969-06-01), Bohl et al.

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