Preparation of diesters from imide/dinitrile compounds

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

Reexamination Certificate

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C560S190000

Reexamination Certificate

active

08053594

ABSTRACT:
Diester compounds are prepared from imide/dinitrile compounds employing a vapor-phase hydrolysis of dinitrile compounds in the presence of alcohol, more particularly from branched dinitrile compounds, such as methylglutaronitrile or branched dinitrile compounds obtained as by-products in a process for the production of adiponitrile by hydrocyanation of butadiene.

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Laeckmann et al., “Synthesis and Biological Evaluation of Aroylguanidines Related to Amiloride as Inhibitors of the Human Platelet Na+/H+Exchanger”, Bioorganic & Medicinal Chemistry, 2002, pp. 1793-1804, vol. 10, No. 6, United Kingdom.
Xue et al., “Transformation of Amides into Esters by the Use of Chlorotrimethylsilane”, Journal of the Chinese Chemical Society, 2004, pp. 359-362, vol. 51, No. 2, Taipei, Taiwan.

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