Block copolymers containing functional groups

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

Reexamination Certificate

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C525S206000, C525S222000, C525S420000, C525S437000, C525S461000, C525S534000, C526S329200, C526S347100, C526S346000

Reexamination Certificate

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08030409

ABSTRACT:
The present invention provides a block copolymer of styrene and an unsaturated cyclic anhydride, such as maleic anhydride, a process for making a copolymer using controlled free radical polymerization in which certain parameters are adjusted to control the microstructure and molecular weight of the copolymer, and a method for using the block copolymer, including as a compatibilizer. Microstructure and molecular weight in the block copolymer can be controlled by adjusting the ratio of stable free radical to initiator. The copolymer can be made in a one step process and has a controlled microstructure that allows one block to be reactive toward several chemical moieties available in engineering polymers and the other block to be fully miscible with polystyrene or polymers miscible with polystyrene or polymers miscible with polystyrene such as polyphenylene ether.

REFERENCES:
patent: 3953404 (1976-04-01), Borman
patent: 4217438 (1980-08-01), Brunelle et al.
patent: 4315086 (1982-02-01), Ueno et al.
patent: 4328327 (1982-05-01), Tanaka et al.
patent: 4581429 (1986-04-01), Solomon et al.
patent: 4600741 (1986-07-01), Aycock et al.
patent: 4605731 (1986-08-01), Evans et al.
patent: 4644053 (1987-02-01), Brunelle et al.
patent: 4732937 (1988-03-01), Sybert
patent: 4748203 (1988-05-01), van Abeelen et al.
patent: 4844163 (1989-07-01), Hazlett et al.
patent: 5141984 (1992-08-01), Orikasa et al.
patent: 5204394 (1993-04-01), Gosens et al.
patent: 5231146 (1993-07-01), Brown et al.
patent: 5274034 (1993-12-01), Morgan et al.
patent: 5290863 (1994-03-01), Brown et al.
patent: 5326813 (1994-07-01), Okada et al.
patent: 5401804 (1995-03-01), Georges et al.
patent: 5449724 (1995-09-01), Moffat et al.
patent: 5910549 (1999-06-01), Matyjaszewski et al.
patent: 6066686 (2000-05-01), Katayama et al.
patent: 6069206 (2000-05-01), Nishihara et al.
patent: 6143848 (2000-11-01), Lee et al.
patent: 6239226 (2001-05-01), Fischer et al.
patent: 6281311 (2001-08-01), Lai et al.
patent: 6444754 (2002-09-01), Chin et al.
patent: 6531547 (2003-03-01), Visger et al.
patent: 6911511 (2005-06-01), Bertin
patent: 2005/0004310 (2005-01-01), Hong et al.
patent: 0 027 274 (1984-08-01), None
patent: WO 99/47575 (1999-09-01), None
RD 332035 (Feb. 1991).
Bell et al., The miscibility of copolymer blends involving the monomers itaconic anhydride, methyl methacrylate, styrene and acrylonitrile, Polymer, 1994, pp. 786-790, V. 35 No. 4, Butterworth-Heinemann Ltd.
Benoit et al., Development of a Universal Alkoxyamine for “Living” Free Radical Polymerizations, Journal of the American Chemical Society, 1999, pp. 3904-3920, V. 121 No. 16, American Chemical Society.
Benoit et al., One-Step Formation of Funcationalized Block Copolymers, Macromolecules, 2000, pp. 1505-1507, V. 33 No. 5, American Checmial Society.
Chiang et al., Polymer Blends of Polyamide-6 and Poly (phenylene oxide) Compatibilized by Styrene-co-Glycidyl Methacrylate, Journal of Applied Polymer Science, 1996, pp. 2411-2421, V. 61, John Wiley & Sons, Inc.
Gan et al., Phase Behavior of Blends of Styrene/Maleic Anhydride Copolymers, Journal of Applied Polymer Science, 1994, pp. 317-331, V. 54, John Wiley & Sons, Inc.
Harth et al., Chain End Funcationalization in Nitroxide-Mediated “Living” Free Radical Polymerizations, Macromolecules, 2001, pp. 3856-3862, V. 34 No. 12, American Chemical Society.
Koulouri et al., Terminal Anhydride Functionalized Polystyrene by Atom Transfer Radical Polymerization Used for hte Compatibilization of Nylon 6/PS Blends, Macromolecules, 1999, pp. 6242-6248, V. 32 No. 19, American Chemical Society.
Merfeld et al., Binary interaction parameters from blends of SMA copolymers with TMPC-PC copolycarbonates, Polymer, 1998, pp. 1999-2009, V. 39 No. 10, Elsevier Science Ltd., Great Britian.
Park et al., Terminal Anhydride Functionalization of Polystyrene, Journal of Polymer Science, Polymer Chemistry, 1991, pp. 1329-1338, V. 29, John Wiley & Sons, Inc.
Park et al., Living Radical Copolymerization of Styrene/Maleic Anhydride, Journal of Polymer Science Part A-Polymer Chemistry, 2000, pp. 2239-2244, V. 38, John Wiley & Sons, Inc.
Yao et al., Continuous Thermal Bulk Copolymerization of Styrene and Maleic Anhydride, Journal of Applied Polymer Science, 1999, pp. 615-622, V. 73, John Wiley & Sons, Inc.
Moad et al., The Chemistry of Free Radical Polymerization, 1995, pp. 277-283, Pergamon.
1 page Patent Abstract of Japanese Patent No. 57-074313 published May 10, 1982.
Cuatepotzo et al., New Controllers for Nitroxide mediated polymerization. A study of electronic effects and of the [nitroxide]/[initiator] ratio on the polymerization control, Submitted for publication to Journal of Polymer Science, 2003 (pending), pp. 1-23.
Saldivar and Gonzalez et al., Synthesis of Novel Copolymers Via Controlled Radical Polymerization (CRP), Slides from Presentation at Second Conference for the Commercialization of Controlled POlymer Synthesis, Dec. 4-5, 2000, 29 pgs., The Knowledge Foundation. Cambridge, USA.

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