Method for producing (meth)acrylates

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

Reexamination Certificate

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C570S217000

Reexamination Certificate

active

08049030

ABSTRACT:
The present invention relates to a process for preparing (meth)acrylates, which comprises the transesterification of an alcohol with a low-boiling ester of (meth)acrylic acid in the presence of catalysts, with the alcohol liberated from the low-boiling ester of (meth)acrylic acid being separated off by distillation, characterized in that the molar ratio of low-boiling ester of (meth)acrylic acid to starting alcohol present in the reaction mixture is increased during the reaction by addition of low-boiling ester of (meth)acrylic acid. The process of the invention makes a particularly inexpensive preparation of (meth)acrylates having a very high purity possible.

REFERENCES:
patent: 4745213 (1988-05-01), Schlosser et al.
patent: 6008371 (1999-12-01), Knebel et al.
patent: 1747924 (2006-03-01), None
patent: 1 094 998 (1967-12-01), None
U.S. Appl. No. 12/667,604, filed Jan. 4, 2010, Schmitt, et al.
U.S. Appl. No. 12/667,822, filed Jan. 5, 2010, Knebel, et al.
U.S. Appl. No. 12/667,538, filed Jan. 4, 2010, Knebel, et al.
U.S. Appl. No. 08/373,422, filed Jan. 17, 1995, Knebel, et al.
U.S. Appl. No. 12/990,095, filed Oct. 28, 2010, Knebel.
Chinese Office Action mailed Feb. 14, 2011w/English translation.

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